First the probability of the sorted input x is computed and than the selected quantiles are calculated and after that plot is produced.
If probs=NULL then the 1%, 5%, 10%, 20%,...., 90%, 95% and 99% quantile is taken.
References
C. Reimann, P. Filzmoser, R.G. Garrett, and R. Dutter: Statistical Data Analysis
Explained. Applied Environmental Statistics with R. John Wiley and Sons, Chichester, 2008.