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seacarb (version 2.3.1)

Kb: Dissociation constant of boric acid (mol/kg)

Description

Dissociation constant of boric acid (mol/kg)

Usage

Kb(S = 35, T = 25, P = 0, pHscale="T")

Arguments

S
Salinity, default is 35
T
Temperature in degrees Celsius, default is 25oC
P
Hydrostatic pressure in bar (surface = 0), default is 0
pHscale
choice of pH scale: "T" for using the total scale, "F" for using the free scale and "SWS" for using the seawater scale, default is total scale

Value

  • KbDissociation constant of boric acid (mol/kg)

encoding

latin1

Details

Note that the arguments can be given as a unique number or as vectors. If the lengths of the vectors are different, the longer vector is retained and only the first value of the other vectors is used. It can therefore be critical to use vectors of the same length. The pressure correction was applied on the seawater scale. Hence, values were first transformed from the total scale to the seawater scale, the pressure correction applied as described by Millero (1995), and the value was transformed back to the required scale (T, F or SWS).

References

Dickson, A. G. 1990 Thermodynamics of the dissociation of boric acid in synthetic seawater from 273.15 to 318.15 K. Deep-Sea Research 375, 755-766. Dickson A. G., Sabine C. L. and Christian J. R., 2007 Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 1-191. DOE 1994 Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water. ORNL/CDIAC-74. Oak Ridge,Tenn.: Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory. Millero F. J., 1995. Thermodynamics of the carbon dioxide system in the oceans. Geochimica Cosmochimica Acta 59: 661-677.

Examples

Run this code
Kb(S=35,T=25,P=0,pHscale="T")

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