seacarb (version 3.3.3)

carb: Parameters of the seawater carbonate system

Description

Returns parameters of the seawater carbonate system.

Usage

carb(flag, var1, var2, S=35, T=25, Patm=1, P=0, Pt=0, Sit=0,
        k1k2="x", kf="x", ks="d", pHscale="T", b="u74", gas="potential", 
        warn="y", eos="eos80", long=1.e20, lat=1.e20)

Value

The function returns a data frame containing the following columns:

S

Salinity

T

Temperature in degrees Celsius

Patm

Surface atmospheric pressure in atm

P

Hydrostatic pressure in bar

pH

pH

CO2

CO2 concentration (mol/kg)

pCO2

"standard" pCO2, CO2 partial pressure computed at in situ temperature and atmospheric pressure (\(\mu\)atm)

fCO2

"standard" fCO2, CO2 fugacity computed at in situ temperature and atmospheric pressure (\(\mu\)atm)

pCO2pot

"potential" pCO2, CO2 partial pressure computed at potential temperature and atmospheric pressure (\(\mu\)atm)

fCO2pot

"potential" fCO2, CO2 fugacity computed at potential temperature and atmospheric pressure (\(\mu\)atm)

pCO2insitu

"in situ" pCO2, CO2 partial pressure computed at in situ temperature and total pressure (atm + hydrostatic) (\(\mu\)atm)

fCO2insitu

"in situ" fCO2, CO2 fugacity computed at in situ temperature and total pressure (atm + hydrostatic) (\(\mu\)atm)

HCO3

HCO3 concentration (mol/kg)

CO3

CO3 concentration (mol/kg)

DIC

DIC concentration (mol/kg)

ALK

ALK, total alkalinity (mol/kg)

OmegaAragonite

Omega aragonite, aragonite saturation state

OmegaCalcite

Omega calcite, calcite saturation state

Arguments

flag

select the couple of variables available. The flags which can be used are:

flag = 1 pH and CO2 given

flag = 2 CO2 and HCO3 given

flag = 3 CO2 and CO3 given

flag = 4 CO2 and ALK given

flag = 5 CO2 and DIC given

flag = 6 pH and HCO3 given

flag = 7 pH and CO3 given

flag = 8 pH and ALK given

flag = 9 pH and DIC given

flag = 10 HCO3 and CO3 given

flag = 11 HCO3 and ALK given

flag = 12 HCO3 and DIC given

flag = 13 CO3 and ALK given

flag = 14 CO3 and DIC given

flag = 15 ALK and DIC given

flag = 21 pCO2 and pH given

flag = 22 pCO2 and HCO3 given

flag = 23 pCO2 and CO3 given

flag = 24 pCO2 and ALK given

flag = 25 pCO2 and DIC given

var1

Value of the first variable in mol/kg, except for pH and for pCO2 in \(\mu\)atm

var2

Value of the second variable in mol/kg, except for pH

S

Salinity

T

Temperature in degrees Celsius

Patm

Surface atmospheric pressure in atm, default is 1 atm

P

Hydrostatic pressure in bar (surface = 0)

Pt

Concentration of total phosphate in mol/kg; set to 0 if NA

Sit

Concentration of total silicate in mol/kg; set to 0 if NA

k1k2

"cw" for using K1 and K2 from Cai & Wang (1998), "l" from Lueker et al. (2000), "m02" from Millero et al. (2002), "m06" from Millero et al. (2006), "m10" from Millero (2010), "mp2" from Mojica Prieto et al. (2002), "p18" from Papadimitriou et al. (2018), "r" from Roy et al. (1993), "sb21" from Shockman & Byrne (2021), "s20" from Sulpis et al. (2020), and "w14" from Waters et al. (2014). "x" is the default flag; the default value is then "l", except if T is outside the range 2 to 35oC and/or S is outside the range 19 to 43. In these cases, the default value is "w14".

kf

"pf" for using Kf from Perez and Fraga (1987) and "dg" for using Kf from Dickson and Riley (1979 in Dickson and Goyet, 1994). "x" is the default flag; the default value is then "pf", except if T is outside the range 9 to 33oC and/or S is outside the range 10 to 40. In these cases, the default is "dg".

ks

"d" for using Ks from Dickson (1990) and "k" for using Ks from Khoo et al. (1977), default is "d"

pHscale

"T" for the total scale, "F" for the free scale and "SWS" for using the seawater scale, default is "T" (total scale)

b

Concentration of total boron. "l10" for the Lee et al. (2010) formulation or "u74" for the Uppstrom (1974) formulation, default is "u74"

gas

used to indicate the convention for INPUT pCO2, i.e., when it is an input variable (flags 21 to 25): "insitu" indicates it is referenced to in situ pressure and in situ temperature; "potential" indicates it is referenced to 1 atm pressure and potential temperature; and "standard" indicates it is referenced to 1 atm pressure and in situ temperature. All three options should give identical results at surface pressure. This option is not used when pCO2 is not an input variable (flags 1 to 15). The default is "potential".

warn

"y" to show warnings when T or S go beyond the valid range for constants; "n" to supress warnings. The default is "y".

eos

"teos10" to specify T and S according to Thermodynamic Equation Of Seawater - 2010 (TEOS-10); "eos80" to specify T and S according to EOS-80.

long

longitude of data point, used when eos parameter is "teos10" as a conversion parameter from absolute to practical salinity.

lat

latitude of data point, used when eos parameter is "teos10".

Author

Heloise Lavigne, James Orr and Jean-Pierre Gattuso

Details

The Lueker et al. (2000) constants for K1 and K2, the Perez and Fraga (1987) constant for Kf and the Dickson (1990) constant for Ks are recommended by Dickson et al. (2007). It is, however, critical to consider that each formulation is only valid for specific ranges of temperature and salinity:

For K1 and K2:

• Cai and Wang (1998): S ranging between 0 and 40 and T ranging between 0.2 and 30oC.

• Lueker et al. (2000): S ranging between 19 and 43 and T ranging between 2 and 35oC.

• Millero et al. (2002): S ranging from 34 to 37 and T ranging between -1.6 and 35oC.

• Millero et al. (2006): S ranging between 0.1 and 50 and T ranging between 1 and 50oC.

• Millero (2010): S ranging between 1 and 50 and T ranging between 0 and 50oC. Millero (2010) provides a K1 and K2 formulation for the seawater, total and free pH scales. Therefore, when this method is used and if P=0, K1 and K2 are computed with the formulation corresponding to the pH scale given in the flag "pHscale".

• Mojica Prieto et al. (2002): S ranging from 5 to 42 and T ranging between 0 and 45oC.

• Papadimitriou et al. (2018): S ranging from 33 to 100 and T ranging between -6 to 25oC.

• Roy et al. (1993): S ranging between 5 and 45 and T ranging between 0 and 45oC.

• Shockman & Byrne (2021): for K2, S ranging from 19.6 to 41 and T ranging between 15 to 35oC. For K1, formulation is that of Waters et al.

• Sulpis et al. (2020): S ranging from 30.7 to 37.6 and T ranging between -1.7 to 31.8oC.

• Waters et al.(2014): S ranging between 1 and 50 and T ranging between 0 and 50oC. Waters (2014) provides a K1 and K2 formulation for the seawater, total and free pH scales. Therefore, when this method is used and if P=0, K1 and K2 are computed with the formulation corresponding to the pH scale given in the flag "pHscale".

For Kf:

• Perez and Fraga (1987): S ranging between 10 and 40 and T ranging between 9 and 33oC.

• Dickson and Riley (1979 in Dickson and Goyet, 1994): S ranging between 0 and 45 and T ranging between 0 and 45oC.

For Ks:

• Dickson (1990): S ranging between 5 and 45 and T ranging between 0 and 45oC.

• Khoo et al. (1977): S ranging between 20 and 45 and T ranging between 5 and 40oC.

The arguments can be given as a unique number or as vectors. If the lengths of the vectors are different, the longer vector is retained and only the first value of the other vectors is used. It is recommended to use either vectors with the same dimension or one vector for one argument and numbers for the other arguments.

Pressure corrections and pH scale:

• For K0, the pressure correction term of Weiss (1974) is used.

• For K1, K2, pK1, pK2, pK3, Kw, Kb, Khs and Ksi, the pressure correction was applied on the seawater scale. Hence, if needed, values were first transformed from the total scale to the seawater scale, the pressure correction applied as described by Millero (1995), and the value was transformed back to the required scale (T, F or SWS).

• For Kf, the pressure correction was applied on the free scale. The formulation of Dickson and Riley (1979 in Dickson and Goyet, 1994) provides Kf on the free scale but that of Perez and Fraga (1987) provides it on the total scale. Hence, in that case, Kf was first transformed from the total scale to the free scale. With both formulations, the pressure correction was applied as described by Millero (1995), and the value was transformed back to the required scale (T, F or SWS).

• For Ks, the pressure correction was applied on the free scale. The pressure correction was applied as described by Millero (1995), and the value was transformed back to the required scale (T, F or SWS).

• For Kn, The pressure correction was applied on the seawater scale. The pressure correction was applied as described by Millero (1995), and the value was transformed back to the required scale (T, F or SWS).

long and lat are used as conversion parameters from absolute to practical salinity: when seawater is not of standard composition, practical salinity alone is not sufficient to compute absolute salinity and vice-versa. One needs to know the density. When long and lat are given, density is inferred from WOA silicate concentration at given location. When they are not, an arbitrary geographic point is chosen: mid equatorial Atlantic. Note that this implies an error on computed salinity up to 0.02 g/kg.

References

Cai W. J., and Wang Y., 1998. The chemistry, fluxes, and sources of carbon dioxide in the estuarine waters of the Satilla and Altamaha Rivers, Georgia. Limnology and Oceanography 43, 657-668.

Dickson A. G. and Riley J. P., 1979 The estimation of acid dissociation constants in seawater media from potentiometric titrations with strong base. I. The ionic product of water. Marine Chemistry 7, 89-99.

Dickson A. G., 1990 Standard potential of the reaction: AgCI(s) + 1/2H2(g) = Ag(s) + HCI(aq), and the standard acidity constant of the ion HSO4 in synthetic sea water from 273.15 to 318.15 K. Journal of Chemical Thermodynamics 22, 113-127.

Dickson A. G., Sabine C. L. and Christian J. R., 2007 Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 1-191.

Khoo H. K., Ramette R. W., Culberson C. H. and Bates R. G., 1977 Determination of Hydrogen ion concentration in seawater from 5 to 40oC: standard potentials at salinities from 20 to 45. Analytical Chemistry 49, 29-34.

Lee K., Tae-Wook K., Byrne R.H., Millero F.J., Feely R.A. and Liu Y-M, 2010 The universal ratio of the boron to chlorinity for the North Pacific and North Atlantoc oceans. Geochimica et Cosmochimica Acta 74 1801-1811.

Lueker T. J., Dickson A. G. and Keeling C. D., 2000 Ocean pCO2 calculated from dissolved inorganic carbon, alkalinity, and equations for K1 and K2: validation based on laboratory measurements of CO2 in gas and seawater at equilibrium. Marine Chemistry 70 105-119.

Millero F. J., 1995. Thermodynamics of the carbon dioxide system in the oceans. Geochimica Cosmochimica Acta 59: 661-677.

Millero F. J., 2010. Carbonate constant for estuarine waters. Marine and Freshwater Research 61: 139-142.

Millero F. J., Graham T. B., Huang F., Bustos-Serrano H. and Pierrot D., 2006. Dissociation constants of carbonic acid in seawater as a function of salinity and temperature. Marine Chemistry 100, 80-84.

Orr J. C., Epitalon J.-M. and Gattuso J.-P., 2015. Comparison of seven packages that compute ocean carbonate chemistry. Biogeosciences 12, 1483-1510.

Perez F. F. and Fraga F., 1987 Association constant of fluoride and hydrogen ions in seawater. Marine Chemistry 21, 161-168.

Roy R. N., Roy L. N., Vogel K. M., Porter-Moore C., Pearson T., Good C. E., Millero F. J. and Campbell D. M., 1993. The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45oC. Marine Chemistry 44, 249-267.

Schockman, K.M., Byrne, R.H., 2021. Spectrophotometric determination of the bicarbonate dissociation constant in seawater, Geochimica et Cosmochimica Acta.

Uppstrom L.R., 1974 The boron/chlorinity ratio of the deep-sea water from the Pacific Ocean. Deep-Sea Research I 21, 161-162.

Waters, J., Millero, F. J., and Woosley, R. J., 2014. Corrigendum to ``The free proton concentration scale for seawater pH'', [MARCHE: 149 (2013) 8-22], Marine Chemistry 165, 66-67.

Weiss, R. F., 1974. Carbon dioxide in water and seawater: the solubility of a non-ideal gas, Mar. Chem., 2, 203-215.

Weiss, R. F. and Price, B. A., 1980. Nitrous oxide solubility in water and seawater, Marine Chemistry, 8, 347-359.

Zeebe R. E. and Wolf-Gladrow D. A., 2001 CO2 in seawater: equilibrium, kinetics, isotopes. Amsterdam: Elsevier, 346 pp.

Examples

## 1. With a couple of variables
carb(flag=8, var1=8.2, var2=0.00234, S=35, T=25, P=0, Patm=1.0, Pt=0, Sit=0,
	pHscale="T", kf="pf", k1k2="l", ks="d", b="u74")

## 2. Using vectors as arguments
flag <- c(8, 2, 8)
var1 <- c(8.2, 7.477544e-06, 8.2)
var2 <- c(0.002343955, 0.001649802, 2400e-6)
S <- c(35, 35, 30)
T <- c(25, 25, 30)
P <- c(0, 0, 0)
Pt <- c(0, 0, 0)
Sit <- c(0, 0, 0)
kf <- c("pf", "pf", "pf")
k1k2 <- c("l", "l", "l")
pHscale <- c("T", "T", "T")
b <- c("l10", "l10", "l10")
carb(flag=flag, var1=var1, var2=var2, S=S, T=T, P=P,
	Pt=Pt, Sit=Sit, kf=kf, k1k2=k1k2, pHscale=pHscale, b=b)

## 3. Special case: when input pH is on NBS scale (not a standard option in seacarb) 
##    -> example for pH-Alk input pair (flag 8) and Cai & Wang (1998) K1,K2 
pHNBS <- c(8.2, 8.1, 8.0)
talk <- c(2300, 2350, 2400) * 1e-6
S <- c(35, 32.5, 30)
T <- c(25, 15, 10)

## 3a. convert pHNBS to pHSWS (using total activity coeff. fH), then use carb with pHscale="SWS"
pHSWS <- pHnbs2sws(pHNBS, S=S, T=T)
carb(flag=8, var1=pHSWS, var2=talk, S=S, T=T, P=0, Patm=1.0, Pt=0, Sit=0,
	pHscale="SWS", kf="pf", k1k2="cw", ks="d", b="u74")

## 3b. conversely for input pairs without pH,  convert computed pH on SWS scale to NBS scale, 
##     with function pHsws2nbs
##    -> example for Alk-DIC input pair (flag 15) and Cai & Wang (1998) K1,K2 
dic <- c(2000., 2030., 2060) * 1e-6
output = carb(flag=15, var1=talk, var2=dic, S=S, T=T, P=0, Patm=1.0, Pt=0, Sit=0,
	pHscale="SWS", kf="pf", k1k2="cw", ks="d", b="u74")
pHNBS  = pHsws2nbs(output$pH, S=S, T=T)

## 4. Test with all flags 
flag <- c((1:15), (21:25))
var1 <- c(8.200000, 7.308171e-06, 7.308171e-06, 7.308171e-06, 7.308171e-06, 
	8.2, 8.2, 8.2, 8.2, 0.001646857, 0.001646857, 0.001646857, 0.0002822957, 
	0.0002822957, 0.00234, 258.2164, 258.2164, 258.2164, 258.2164, 258.2164 )
var2 <- c(7.308171e-06, 0.001646857, 0.0002822957, 0.00234, 0.001936461, 
	0.001646857, 0.0002822957, 0.00234, 0.001936461, 0.0002822957, 
	0.00234, 0.001936461,  0.00234, 0.001936461, 0.001936461, 8.2, 
	0.001646857, 0.0002822957, 0.00234, 0.001936461)
carb(flag=flag, var1=var1, var2=var2)

## 5. Test using a data frame 
data(seacarb_test_P0)	#test data set for P=0 (surface)
tab <- seacarb_test_P0[14:19,]

## 5a. method 1 using the column numbers
carb(flag=tab[[1]], var1=tab[[2]], var2=tab[[3]], S=tab[[4]], T=tab[[5]], 
P=tab[[6]], Sit=tab[[8]], Pt=tab[[7]])

## 5b. method 2 using the column names
carb(flag=tab$flag, var1=tab$var1, var2=tab$var2, S=tab$S, T=tab$T, 
P=tab$P, Sit=tab$Sit, Pt=tab$Pt)